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Double-charge-transfer spectroscopy of O2 2+ : Band analyses of low-lying repulsive states
https://rikkyo.repo.nii.ac.jp/records/10717
https://rikkyo.repo.nii.ac.jp/records/10717b06a2ea6-b457-43c3-8449-358718191977
名前 / ファイル | ライセンス | アクション |
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PRA_70_5.pdf (91.4 kB)
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Item type | 学術雑誌論文 / Journal Article(1) | |||||
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公開日 | 2015-01-14 | |||||
タイトル | ||||||
タイトル | Double-charge-transfer spectroscopy of O2 2+ : Band analyses of low-lying repulsive states | |||||
タイトル | ||||||
言語 | en | |||||
タイトル | Double-charge-transfer spectroscopy of O2 2+ : Band analyses of low-lying repulsive states | |||||
言語 | ||||||
言語 | eng | |||||
資源タイプ | ||||||
資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||
資源タイプ | journal article | |||||
著者 |
Furuhashi, Osamu
× Furuhashi, Osamu× Kinugawa, Tohru× Hirayama, Takato× Koizumi, Tetsuo× Yamada, Chikashi× Ohtani, Shunsuke |
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抄録 | ||||||
内容記述タイプ | Abstract | |||||
内容記述 | The double-charge-transfer (DCT) spectrum of O 2 2+ has been recorded at 140meV resolution using 1.5keV H + projectiles. Electronic bands of the low-lying triplet states, namely AΣ u + 3 , WΔ u 3 , BΠ g 3 , and B ′ Σ u − 3 , have been resolved. Assuming that the observed bands directly reflect the Franck-Condon (FC) profiles, potential-energy curves of the AΣ u + 3 , WΔ u 3 , and B ′ Σ u − 3 states within the FC region are determined based on the reflection approximation. For a quantitative check of the results, complete active space self-consistent-field and multireference configuration-interaction calculations have been performed to predict the potential-energy curves and the FC profiles. The calculated energy curves agree well with the experimentally derived ones. The theoretical FC profiles reproduced well the band shapes observed by both present DCT and previous Doppler-free kinetic-energy release methods. However, our results cast doubt on the previous assignment of luminescence to the O 2 2+ BΠ g 3 →AΣ u + 3 transition and the observed bound level of the AΣ u + 3 state by the previous threshold photoelectron coincidence experiment. | |||||
書誌情報 |
Physical Review A en : Physical Review A 巻 70, 号 5, p. 052501, 発行日 2004-11 |
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出版者 | ||||||
出版者 | American Physical Society | |||||
ISSN | ||||||
収録物識別子タイプ | ISSN | |||||
収録物識別子 | 1050-2947 | |||||
書誌レコードID | ||||||
収録物識別子タイプ | NCID | |||||
収録物識別子 | AA10764867 | |||||
DOI | ||||||
関連タイプ | isIdenticalTo | |||||
識別子タイプ | DOI | |||||
関連識別子 | info:doi/10.1103/PhysRevA.70.052501 | |||||
権利 | ||||||
権利情報 | © 2004 The American Physical Society | |||||
著者版フラグ | ||||||
出版タイプ | VoR | |||||
出版タイプResource | http://purl.org/coar/version/c_970fb48d4fbd8a85 |